Ozone Hole

Ozone hole splits in two
Video
Hole over Antarctica
also markedly smaller
this year, scientists say
False-color satellite imagery from Sept. 26 shows the double ozone hole as dark blue splotches around Antarctica. Click on the video button to watch an time-lapse animation of the ozone hole’s development.

ASSOCIATED PRESS
WASHINGTON, Sept. 30 — The ozone hole over Antarctica is markedly smaller this year than in the last few years and has split in two, government scientists reported Monday. The so-called “hole,” actually an area of thinner than normal ozone, was measured at 6 million square miles in September. That compares with around 9 million square miles on September measurements over the last six years, according to researchers at the National Oceanic and Atmospheric Administration and National Aeronautics and Space Agency.

the stratosphere over the southern hemisphere was unusually disturbed this year by the wind, causing the hole to split into two separate holes. WHILE OZONE at ground level is considered a pollutant, the layer of ozone high in the stratosphere is vital to life because it blocks dangerous radiation coming from the sun. Thinning of the ozone layer could lead to a rise in skin cancer, experts warn. Aerosols and other chemicals are blamed for the thinning, and treaties banning those ingredients are expected to help the layer recover over time.
This year’s improvement was attributed to warmer than normal temperatures around the edge of the polar vortex, or circular wind pattern that forms annually in the stratosphere over Antarctica, according to Paul Newman, a lead ozone researcher at NASA’s Goddard Space Flight Center in Greenbelt, Maryland.
Craig Long, a meteorologist at the NOAA Climate Prediction Center, said the stratosphere over the southern hemisphere was unusually disturbed this year by the wind, causing the hole to split into two separate holes.
In 2001 the Antarctic ozone hole reached a maximum size of more than 10.2 million square miles, larger than the entire area of North America, including the United States, Canada and Mexico combined. In the year 2000, it briefly approached 11.5 million square miles. The last time the ozone hole was as small as it is this year was in 1988, and that was also due to warm temperatures.
Newman explained that while “chlorine and bromine chemicals cause the ozone hole, the temperature is also a key factor in ozone loss.”
The coldest temperatures over the South Pole occur in August and September. Thin clouds form in these cold conditions, and chemical reactions on the cloud particles help chlorine and bromine gases to rapidly destroy ozone. By early October, temperatures typically start to warm and the ozone layer starts to recover.

What is the ozone?
Earth’s defense against solar radiation
The ozone is an atmospheric gas which filters out a harmful form of solar radiation known as ultraviolet radiation. About 90% of the ozone in our atmosphere is contained in the stratosphere (the region from about 30,000 feet to 180,000 feet above the Earth’s surface).


How is it made?
Ozone is produced by intense ultraviolet (UV) radiation in the upper stratosphere, which causes oxygen molecules (O2) to reform as ozone molecules (O3). The ozone molecule spends most of its life absorbing UV.


How is it destroyed?
Ozone is destroyed when it reacts with one of a variety of chemicals in the stratosphere such as chlorine, nitrogen, bromine or hydrogen. Such chemicals come primarily from man-made chlorine and bromine compounds produced for refrigerants, aerosol sprays, and solvents.


Why study at the poles?
A number of factors found only at the poles increase the likelihood of ozone depletion. As the air in the stratosphere cools and descends during the winter, strong winds create a vortex around each pole. This air is effectively isolated the rest of the atmosphere. Within this vortex form polar stratospheric clouds (PSCs). Studies indicate that the chemical composition of these stratospheric clouds – and the extremely low temperature – provide the perfect environment for breaking ozone molecules.


Antarctica’s ozone hole
Ozone levels over Antarctica fall to abnormally low values between August and late November, destroying about 95% of the ozone in the lower stratosphere. In 1987, and from 1989-95, the hole covered the entire continent and part of the surrounding ocean. There is currently no ozone hole at the North Pole, but a recent study determined that ozone losses of over 60 percent occurred in the Arctic stratosphere at an elevation near 60,000 feet during the winter of 1998/1999.


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Volcanic Landforms,Volcanoes and Plate Tectonics

Volcanic Landforms

Volcanic landforms are controlled by the geological processes that form them and act on them after they have formed. Thus, a given volcanic landform will be characteristic of the types of material it is made of, which in turn depends on the prior eruptive behavior of the volcano. Although later processes can modify the original landform, we should be able to find clues in the modified form that lead us to conclusions about the original formation process. Here we discuss the major volcanic landforms and how they are formed, and in some cases, later modified. Most of this material will be discussed with reference to slides shown in class that illustrate the essential features of each volcanic landform.

Shield Volcanoes

  • A shield volcano is characterized by gentle upper slopes (about 5o) and somewhat steeper lower slopes (about 10o).

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  • Shield volcanoes are composed almost entirely of relatively thin lava flows built up over a central vent.

  • Most shields were formed by low viscosity basaltic magma that flows easily down slope away form the summit vent.

  • The low viscosity of the magma allows the lava to travel down slope on a gentle slope, but as it cools and its viscosity increases, its thickness builds up on the lower slopes giving a somewhat steeper lower slope.

  • Most shield volcanoes have a roughly circular or oval shape in map view.

  • Very little pyroclastic material is found within a shield volcano, except near the eruptive vents, where small amounts of pyroclastic material accumulate as a result of fire fountaining events.

  • Shield volcanoes thus form by relatively non-explosive eruptions of low viscosity basaltic magma.

  • Vents for most shield volcanoes are central vents, which are circular vents near the summit. Hawaiian shield volcanoes also have flank vents, which radiate from the summit and take the form of en-echelon fractures or fissures, called rift zones, from which lava flows are emitted. This gives Hawaiian shield volcanoes like Kilauea and Mauna Loa their characteristic oval shape in map view.
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Stratovolcanoes (also called Composite Volcanoes)

  • Have steeper slopes than shield volcanoes, with slopes of 6 to 10o low on the flanks to 30o near the top.

  • The steep slope near the summit is due partly to thick, short viscous lava flows that do not travel far down slope from the vent.

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  • The gentler slopes near the base are due to accumulations of material eroded from the volcano and to the accumulation of pyroclastic material.

  • Stratovolcanoes show inter-layering of lava flows and pyroclastic material, which is why they are sometimes called composite volcanoes. Pyroclastic material can make up over 50% of the volume of a stratovolcano.

  • Lavas and pyroclastics are usually andesitic to rhyolitic in composition.

  • Due to the higher viscosity of magmas erupted from these volcanoes, they are usually more explosive than shield volcanoes.

  • Stratovolcanoes sometimes have a crater at the summit that is formed by explosive ejection of material from a central vent. Sometimes the craters have been filled in by lava flows or lava domes, sometimes they are filled with glacial ice, and less commonly they are filled with water.

  • Long periods of repose (times of inactivity) lasting for hundreds to thousands of years, make this type of volcano particularly dangerous, since many times they have shown no historic activity, and people are reluctant to heed warnings about possible eruptions.

Tephra Cones (also called Cinder Cones)

  • Tephra cones are small volume cones consisting predominantly of tephra that result from strombolian eruptions. They usually consist of basaltic to andesitic material.

  • They are actually fall deposits that are built surrounding the eruptive vent.

  • Slopes of the cones are controlled by the angle of repose (angle of stable slope for loose unconsolidated material) and are usually between about 25 and 35o.

  • They show an internal layered structure due to varying intensities of the explosions that deposit different sizes of pyroclastics.

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  • On young cones, a depression at the top of the cone, called a crater, is evident, and represents the area above the vent from which material was explosively ejected. Craters are usually eroded away on older cones.

  • If lava flows are emitted from tephra cones, they are usually emitted from vents on the flank or near the base of the cone during the later stages of eruption.

  • Cinder and tephra cones usually occur around summit vents and flank vents of stratovolcanoes.

  • An excellent example of cinder cone is Parícutin Volcano in Mexico. This volcano was born in a farmers corn field in 1943 and erupted for the next 9 years. Lava flows erupted from the base of the cone eventually covered two towns.

  • Cinder cones often occur in groups, where tens to hundreds of cones are found in one area.

Maars
  • Maars result from phreatic or phreatomagmatic activity, wherein magma heats up water in the groundwater system, pressure builds as the water to turns to steam, and then the water and preexisting rock (and some new magma if the eruption is phreatomagmatic) are blasted out of the ground to form a tephra cone with gentle slopes.

maars.gif(10336 bytes)
    Parts of the crater walls eventually collapse back into the crater, the vent is filled with loose material, and, if the crater still is deeper than the water table, the crater fills with water to form a lake, the lake level coinciding with the water table.

Lava Domes (also called Volcanic Domes)

  • Volcanic Domes result from the extrusion of highly viscous, gas poor andesitic and rhyolitic lava. Since the viscosity is so high, the lava does not flow away from the vent, but instead piles up over the vent.

  • Blocks of nearly solid lava break off the outer surface of the dome and roll down its flanks to form a breccia around the margins of domes.

  • The surface of volcanic domes are generally very rough, with numerous spines that have been pushed up by the magma from below.

volcdome.gif(16355 bytes)
  • Most dome eruptions are preceded by explosive eruptions of more gas rich magma, producing a tephra cone into which the dome is extruded.
  • Volcanic domes can be extremely dangerous. because they form unstable slopes that may collapse to expose gas-rich viscous magma to atmospheric pressure. This can result in lateral blasts or Pelean type pyroclastic flow (nuée ardentes) eruptions.

Craters and Calderas

  • Craters are circular depressions, usually less than 1 km in diameter, that form as a result of explosions that emit gases and tephra.

  • Calderas are much larger depressions, circular to elliptical in shape, with diameters ranging from 1 km to 50 km. Calderas form as a result of collapse of a volcanic structure. The collapse results from evacuation of the underlying magma chamber.

  • In shield volcanoes, like in Hawaii, the evacuation of the magma chamber is a slow drawn out processes, wherein magma is withdrawn to erupt on from the rift zones on the flanks.

  • In stratovolcanoes the collapse and formation of a caldera results from rapid evacuation of the underlying magma chamber by voluminous explosive eruptions that form extensive fall deposits and pyroclastic flows.

  • Calderas are often enclosed depressions that collect rain water and snow melt, and thus lakes often form within a caldera.

  • Crater Lake Caldera in southern Oregon is an 8 km diameter caldera containing a lake The caldera formed about 6800 years ago as a result of the eruption of about 75 km3 of rhyolite magma in the form of tephra, found as far away as Canada, accompanied by pyroclastic flows that left thick deposits of tuff on the flanks of the volcano. Subsequent eruptions have built a cinder cone on the floor of the caldera, which now forms an island called Wizard Island.
  • Larger calderas have formed within the past million years in the western United States. These include Yellowstone Caldera in Wyoming, Long Valley Caldera in eastern California, and Valles Caldera in New Mexico.
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  • The Yellowstone caldera is an important example, as it illustrates the amount of repose time that might be expected from large rhyolitic systems, and the devastating effect caldera forming eruptions can have on widespread areas.
    • Yellowstone Caldera which occupies most of Yellowstone National Park, is actually the third caldera to form in the area within the past 2 million years. The three calderas formed at 2.0 million years ago, 1.3 million years ago, and the latest at 600,000 years ago. Thus the repose time is on the average about 650,000 years.
    • Tephra fall deposits from the latest eruption are found in Louisiana and into the Gulf of Mexico, and covered much of the Western part of the United States.
    • The eruption 600,000 years ago produced about 1000 km3 of rhyolite (in comparison, the eruption of Mt. St. Helens in May of 1980 produced only 0.75 km3.

    • Magma still underlies Yellowstone caldera, as evidenced by the large number of hot springs and geysers in the area.

Resurgent Domes

  • After the formation of a caldera by collapse, magma is sometimes re-injected into the area below the caldera. This can result in uplift of one or more areas within the caldera to form a resurgent dome. Two such resurgent domes formed in the Yellowstone caldera, as shown above.

  • If magma leaks back to the surface during this resurgent doming, then eruptions of small volcanic domes can occur in the area of the resurgent domes.

Geysers, Fumaroles and Hot Springs
  • A fumarole is vent where gases, either from a magma body at depth, or steam from heated groundwater, emerges at the surface of the Earth. Since most magmatic gas is H2O vapor, and since heated groundwater will produce H2O vapor, fumaroles will only be visible if the water condenses. (H2O vapor is invisible, unless droplets of liquid water have condensed).

  • Hot springs or thermal springs are areas where hot water comes to the surface of the Earth. Cool groundwater moves downward and is heated by a body of magma or hot rock. A hot spring results if this hot water can find its way back to the surface, usually along fault zones.

  • A geyser results if the hot spring has a plumbing system that allows for the accumulation of steam from the boiling water. When the steam pressure builds so that it is higher than the pressure of the overlying water in the system, the steam will move rapidly toward the surface, causing the eruption of the overlying water. Some geysers, like Old Faithful in Yellowstone Park, erupt at regular intervals. The time between eruptions is controlled by the time it takes for the steam pressure to build in the underlying plumbing system.

Plateau Basalts or Flood Basalts

  • Plateau or Flood basalts are extremely large volume outpourings of low viscosity basaltic magma from fissure vents. The basalts spread huge areas of relatively low slope and build up plateaus.

  • The only historic example occurred in Iceland in 1783, where the Laki basalt erupted from a 32 km long fissure and covered an area of 588 km2 with 12 km3 of lava. As a result of this eruption, homes were destroyed, livestock were killed, and crops were destroyed, resulting in a famine that killed 9336 people.

  • In Oregon and Washington of the northwestern U.S., the Columbia River Basalts represent a series of lava flows all erupted within about 1 million years 12 million years ago. One of the basalt flows, the Roza flow, was erupted over a period of a few weeks traveled about 300 km and has a volume of about 1500 km3.
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Volcanoes and Plate Tectonics

Global Distribution of Volcanoes

In the discussion we had last lecture about how magmas form, we pointed out that since the upper parts of the Earth are solid, special conditions are necessary to form magmas. These special conditions do not exist everywhere beneath the surface, and thus volcanism does not occur everywhere. If we look at the global distribution of volcanoes we see that volcanism occurs four principal settings.

  1. Along divergent plate boundaries, such as Oceanic Ridges or spreading centers.
  2. In areas of continental extension (that may become divergent plate boundaries in the future).
  3. Along converging plate boundaries where subduction is occurring.
  4. And, in areas called “hot spots” that are usually located in the interior of plates, away from the plate margins.
  • Diverging Plate Margins
    Active volcanism is currently taking place along all of oceanic ridges, but most of this volcanism is submarine volcanism and does not generally pose a threat to humans. One of the only places where an oceanic ridge reaches above sea level is at Iceland, along the Mid-Atlantic Ridge. Here, most eruptions are basaltic in nature, but, many are explosive strombolian types or explosive phreatic or phreatomagmatic types. As seen in the map to the right, the Mid-Atlantic ridge runs directly through Iceland
    • Volcanism also occurs in continental areas that are undergoing episodes of extensional deformation. A classic example is the East African Rift Valley, where the African plate is being split. The extensional deformation occurs because the underlying mantle is rising from below and stretching the overlying continental crust. Upwelling mantle may melt to produce magmas, which then rise to the surface, often along normal faults produced by the extensional deformation. Basaltic and rhyolitic volcanism is common in these areas. In the same area, the crust has rifted apart along the Red Sea, and the Gulf of Aden to form new oceanic ridges. This may also be the fate of the East African Rift Valley at some time in the future.
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    • Other areas where extensional deformation is occurring within the crust is Basin and Range Province of the western U.S. (eastern California, Nevada, Utah, Idaho, western Wyoming and Arizona) and the Rio Grande Rift, New Mexico. These are also areas of recent basaltic and rhyolitic volcanism.
  • Converging Plate Margin
    All around the Pacific Ocean, is a zone often referred to as the Pacific Ring of Fire, where most of the world’s most active and most dangerous volcanoes occur. The Ring of Fire occurs because most of the margins of the Pacific ocean coincide with converging margins along which subduction is occurring
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    The convergent boundary along the coasts of South America, Central America, Mexico, the northwestern U.S. (Northern California, Oregon, & Washington), western Canada, and eastern Alaska, are boundaries along which oceanic lithosphere is being subducted beneath continental lithosphere. This has resulted in the formation of continental volcanic arcs that form the Andes Mountains, the Central American Volcanic Belt, the Mexican Volcanic Belt, the Cascade Range, and the Alaskan volcanic arc.
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    The Aleutian Islands (west of Alaska), the Kurile-Kamchatka Arc, Japan, Philippine Islands, and Marianas Islands, New Zealand, and the Indonesian Islands, along the northern and western margins of the Pacific Ocean are zones where oceanic lithosphere is being subducted beneath oceanic lithosphere. These are all island arcs.
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    • As discussed previously, most of the magmas generated as a result of subduction are andesitic magmas, and thus volcanism in these convergent margin areas is predominantly andesitic volcanism.
    • But, through a complex process, known as magmatic differentiation, andesitic magma can change to rhyolitic magma. Thus, rhyolitic volcanism is also common in these areas.
    • Because these magmas are often gas rich and have all have relatively high viscosity, eruptions in these areas tend to be violent, with common Strombolian, Vulcanian, Plinian and Pelean eruptions.
    • Volcanic landforms tend to be cinder cones, stratovolcanoes, volcanic domes, and calderas.
    • Repose periods between eruptions tend to be hundreds to thousands of years, thus giving people living near these volcanoes a false sense of security.
  • Hot Spots
    Volcanism also occurs in areas that are not associated with plate boundaries, in the interior of plates. These are most commonly associated with what is called a hot spot. Hot spots appear to result from plumes of hot mantle material upwelling toward the surface, independent of the convection cells though to cause plate motion. Hot spots tend to be fixed in position, with the plates moving over the top. As the rising plume of hot mantle moves upward it begins to melt to produce magmas. These magmas then rise to the surface producing a volcano. But, as the plate carrying the volcano moves away from the position over the hot spot, volcanism ceases and new volcano forms in the position now over the hot spot. This tends to produce chains of volcanoes or seamounts (former volcanic islands that have eroded below sea level).

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    Volcanism resulting from hotspots occurs in both the Atlantic and Pacific ocean, but are more evident on the sea floor of the Pacific Ocean, because the plates here move at higher velocity than those under the Atlantic Ocean. A hot spot trace shows up as a linear chain of islands and seamounts, many of which can be seen in the Pacific Ocean. The Hawaiian Ridge is one such hot spot trace. Here the Big Island of Hawaii is currently over the hot spot, the other Hawaiian islands still stand above sea level, but volcanism has ceased. Northwest of the Hawaiian Islands, the volcanoes have eroded and are now seamounts.
    The ages of volcanic rocks increase along the Hawaiian Ridge to the northwest of Hawaii. The prominent bend observed where the Hawaiian Ridge intersects the Emperor Seamount chain has resulted from a change in the direction of plate motion over the hot spot. Note that when the Emperor Seamount chain was produced, the plate must have been moving in a more northerly direction. The age of the volcanic rocks at the bend is about 50 million years.
LinearIslands.GIF (19512 bytes)Source:http://www.tulane.edu
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Volcanic Gases and Their Effects

Eruption cloud of volcanic gases from Pu`u `O`o vent on Kilauea Volcano, Hawai`i
Sulfur dioxide gas creates air pollution in Hawai’i

Volcanic gases are the driving force of eruptions

Magma contains dissolved gases that are released into the atmosphere during eruptions. Gases are also released from magma that either remains below ground (for example, as an intrusion) or is rising toward the surface. In such cases, gases may escape continuously into the atmosphere from the soil, volcanic vents, fumaroles, and hydrothermal systems.

At high pressures deep beneath the earth’s surface, volcanic gases are dissolved in molten rock. But as magma rises toward the surface where the pressure is lower, gases held in the melt begin to form tiny bubbles. The increasing volume taken up by gas bubbles makes the magma less dense than the surrounding rock, which may allow the magma to continue its upward journey. Closer to the surface, the bubbles increase in number and size so that the gas volume may exceed the melt volume in the magma, creating a magma foam. The rapidly expanding gas bubbles of the foam can lead to explosive eruptions in which the melt is fragmented into pieces of volcanic rock, known as tephra. If the molten rock is not fragmented by explosive activity, a lava flow will be generated.

Dead trees at base of Mammoth Mountain, Long Valley caldera, California
Carbon dioxide gas kills trees in California
Together with the tephra and entrained air, volcanic gases can rise tens of kilometers into Earth’s atmosphere during large explosive eruptions. Once airborne, the prevailing winds may blow the eruption cloud hundreds to thousands of kilometers from a volcano. The gases spread from an erupting vent primarily as acid aerosols (tiny acid droplets), compounds attached to tephra particles, and microscopic salt particles.
Eruption column at Mount St. Helens on MAy 18, 1980
Explosive eruption, Mount St. Helens
Volcanic gases undergo a tremendous increase in volume when magma rises to the Earth’s surface and erupts. For example, consider what happens if one cubic meter of 900°C rhyolite magma containing five percent by weight of dissolved water were suddenly brought from depth to the surface. The one cubic meter of magma now would occupy a volume of 670 m3 as a mixture of water vapor and magma at atmospheric pressure (Sparks et. al., 1997)! The one meter cube at depth would increase to 8.75 m on each side at the surface. Such enormous expansion of volcanic gases, primarily water, is the main driving force of explosive eruptions.

Types of volcanic gases

The most abundant gas typically released into the atmosphere from volcanic systems is water vapor (H20), followed by carbon dioxide (C02) and sulfur dioxide (S02). Volcanoes also release smaller amounts of others gases, including hydrogen sulfide (H2S), hydrogen (H2), carbon monoxide (CO), hydrogen chloride (HCL), hydrogen fluoride (HF), and helium (He).

Examples of volcanic gas compositions, in volume percent concentrations
(from Symonds et. al., 1994)

Volcano
Tectonic Style
Temperature
Kilauea Summit
Hot Spot
1170°C
Erta` Ale
Divergent Plate
1130°C
Momotombo
Convergent Plate
820°C
H20 37.1 77.2 97.1
C02 48.9 11.3 1.44
S02 11.8 8.34 0.50
H2 0.49 1.39 0.70
CO 1.51 0.44 0.01
H2S 0.04 0.68 0.23
HCl 0.08 0.42 2.89
HF — — 0.26

Potential effects of volcanic gases

The volcanic gases that pose the greatest potential hazard to people, animals, agriculture, and property are sulfur dioxide, carbon dioxide, and hydrogen fluoride. Locally, sulfur dioxide gas can lead to acid rain and air pollution downwind from a volcano. Globally, large explosive eruptions that inject a tremendous volume of sulfur aerosols into the stratosphere can lead to lower surface temperatures and promote depletion of the Earth’s ozone layer. Because carbon dioxide gas is heavier than air, the gas may flow into in low-lying areas and collect in the soil. The concentration of carbon dioxide gas in these areas can be lethal to people, animals, and vegetation. A few historic eruptions have released sufficient fluorine-compounds to deform or kill animals that grazed on vegetation coated with volcanic ash; fluorine compounds tend to become concentrated on fine-grained ash particles, which can be ingested by animals.

Sulfur dioxide (SO2)

The effects of SO2 on people and the environment vary widely depending on (1) the amount of gas a volcano emits into the atmosphere; (2) whether the gas is injected into the troposphere or stratosphere; and (3) the regional or global wind and weather pattern that disperses the gas. Sulfur dioxide (SO2) is a colorless gas with a pungent odor that irritates skin and the tissues and mucous membranes of the eyes, nose, and throat. Sulfur dioxide chiefly affects upper respiratory tract and bronchi. The World Health Organization recommends a concentration of no greater than 0.5 ppm over 24 hours for maximum exposure. A concentration of 6-12 ppm can cause immediate irritation of the nose and throat; 20 ppm can cause eye irritation; 10,000 ppm will irritate moist skin within minutes.

Emission rates of SO2 from an active volcano range from <20 tonnes/day to >10 million tonnes/day according to the style of volcanic activity and type and volume of magma involved. For example, the large explosive eruption of Mount Pinatubo on 15 June 1991 expelled 3-5 km 3 of dacite magma and injected about 17 million tonnes of SO2 into the stratosphere. The sulfur aerosols resulted in a 0.5-0.6°C cooling of the Earth’s surface in the Northern Hemisphere. The sulfate aerosols also accelerated chemical reactions that, together with the increased stratospheric chlorine levels from human-made chlorofluorocarbon (CFC) pollution, destroyed ozone and led to some of the lowest ozone levels ever observed in the atmosphere.

At Kilauea Volcano, the recent effusive eruption of about 0.0005 km3/day (500,000 m3) of basalt magma releases about 2,000 tonnes of SO2 into the lower troposphere. Downwind from the vent, acid rain and air pollution is a persistent health problem when the volcano is erupting.

Geologist with gas mask on rim of Pu`u `O`o crater, Kilauea Volcano, Hawai`i
SO2 causes air pollution
Volcanic smog
Eruptions of Kilauea Volcano release large quantities of sulfur dioxide gas into the atmosphere that can lead to volcanic air pollution on the Island of Hawai`i. Sulfur dioxide gas reacts chemically with sunlight, oxygen, dust particles, and water to form volcanic smog known as vog. Details.
Space Shuttle image over South America, Mission STS 43
SO2 effects Earth’s surface temperature
Global cooling and ozone depletion
Measurements from recent eruptions such as Mount St. Helens, Washington (1980), El Chichon, Mexico (1982), and Mount Pinatubo, Philippines (1991), clearly show the importance of sulfur aerosols in modifying climate, warming the stratosphere, and cooling the troposphere. Research has also shown that the liquid drops of sulfuric acid promote the destruction of the Earth’s ozone layer. Details.

Hydrogen sulfide (H2S)

Hydrogen sulfide (H2S) is a colorless, flammable gas with a strong offensive odor. It is sometimes referred to as sewer gas. At low concentrations it can irritate the eyes and acts as a depressant; at high concentrations it can cause irritation of the upper respiratory tract and, during long exposure, pulmonary edema. A 30-minute exposure to 500 ppm results in headache, dizziness, excitement, staggering gait, and diarrhea, followed sometimes by bronchitis or bronchopneumonia.

Carbon dioxide (CO2)

Volcanoes release more than 130 million tonnes of CO2 into the atmosphere every year. This colorless, odorless gas usually does not pose a direct hazard to life because it typically becomes diluted to low concentrations very quickly whether it is released continuously from the ground or during episodic eruptions. But in certain circumstances, CO2 may become concentrated at levels lethal to people and animals. Carbon dioxide gas is heavier than air and the gas can flow into in low-lying areas; breathing air with more than 30% CO2 can quickly induce unconsciousness and cause death. In volcanic or other areas where CO2 emissions occur, it is important to avoid small depressions and low areas that might be CO2 traps. The boundary between air and lethal gas can be extremely sharp; even a single step upslope may be adequate to escape death.

When a burning piece of wood is lowered into a hole that has a high concentration of CO2, the fire goes out. Such a condition can be lethal to people and animals.
Burning torch on end of stick, Nyamuragira Volcano, Zaire
Burning cloth…
Smoldering cloth on end of stick, Nyamuragira Volcano, Zaire
CO2 puts fire out…
Small dead mammal in depression of a lava flow
CO2 kills small mammal…
Air with 5% CO2 causes perceptible increased respiration; 6-10% results in shortness of breath, headaches, dizziness, sweating, and general restlessness; 10-15% causes impaired coordination and abrupt muscle contractions; 20-30% causes loss of consciousness and convulsions; over 30% can cause death (Hathaway et. al., 1991).

Comparison of CO2 emissions from volcanoes vs. human activities.
Scientists have calculated that volcanoes emit between about 130-230 million tonnes (145-255 million tons) of CO2 into the atmosphere every year (Gerlach, 1999, 1991). This estimate includes both subaerial and submarine volcanoes, about in equal amounts. Emissions of CO2 by human activities, including fossil fuel burning, cement production, and gas flaring, amount to about 27 billion tonnes per year (30 billion tons) [ ( Marland, et al., 2006) – The reference gives the amount of released carbon (C), rather than CO2, through 2003.]. Human activities release more than 130 times the amount of CO2 emitted by volcanoes–the equivalent of more than 8,000 additional volcanoes like Kilauea (Kilauea emits about 3.3 million tonnes/year)! (Gerlach et. al., 2002)

Historical examples of the effects of carbon dioxide gas

Hydrogen Chloride (HCl)

Chlorine gas is emitted from volcanoes in the form of hydrochloric acid (HCl). Exposure to the gas irritates mucous membranes of the eyes and respiratory tract. Concentrations over 35 ppm cause irritation of the throat after short exposure; >100 ppm results in pulmonary edema, and often laryngeal spasm. It also causes acid rain downwind from volcanoes because HCl is extremely soluble in condensing water droplets and it is a very “strong acid” (it dissociates extensively to give H+ ions in the droplets).

Hydrogen Fluoride (HF)

Fluorine is a pale yellow gas that attaches to fine ash particles, coats grass, and pollutes streams and lakes. Exposure to this powerful caustic irritant can cause conjunctivitis, skin irritation, bone degeneration and mottling of teeth. Excess fluorine results in a significant cause of death and injury in livestock during ash eruptions. Even in areas that receive just a millimeter of ash, poisoning can occur where the fluorine content of dried grass exceeds 250 ppm. Animals that eat grass coated with fluorine-tainted ash are poisoned. Small amounts of fluorine can be beneficial, but excess fluorine causes fluorisis, an affliction that eventually kills animals by destroying their bones. It also promotes acid rain effects downwind of volcanoes, like HCl.

Secondary Gas Emissions

Another type of gas release occurs when lava flows reach the ocean. Extreme heat from molten lava boils and vaporizes seawater, leading to a series of chemical reactions. The boiling and reactions produce a large white plume, locally known as lava haze or laze, containing a mixture of hydrochloric acid and concentrated seawater.

White acid-rich steam plume rises from lava flows entering the sea
Acid-rich plumes
Lava haze or laze
Hydrochloric acid forms when lava enters the ocean boiling and vaporizing the sea water. Chloride in the sea salt combines with hydrogen in the water to form hydrochloric acid in the plume. This is a short-lived local phenomenon that only affects people or vegetation directly under the plume. Details.

source:http://volcanoes.usgs.gov

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Frontal or Cyclonic Rain

Frontal (or Cyclonic) Rain is caused by cyclonic activity and it occurs along the fronts of the cyclone. It is formed when two masses of air of different temperature, humidity and density meets. For example meeting of moisture laden warm tropical wind with a polar air mass. A layer separating air masses  is called the front. Front are of two types , the warm front and the cold front. At the warm front, the warm lighter wind rises gently over the heavier cold air, which being heavy stays close to the ground. As the warm air rises, it cools, and the moisture present in it condenses to form clouds altostratus clouds. This rain falls steadily for a few hours to a few days.

Effect on Agriculture

At the cold front, the cold air forces the warm air to rise aggressively causing its moisture to condense quickly, which results in the formation of cumulonimbus clouds. The rain from this cloud is usually heavy and of short duration.

Falling raindrops are often depicted in cartoons or anime as “teardrop-shaped” round at the bottom and narrowing towards the top but this is incorrect. Only drops of water dripping from some sources are tear-shaped at the moment of formation. Small raindrops are nearly spherical. Larger ones become increasingly flattened on the bottom, like hamburger buns; very large ones are shaped like parachutes. The shape of raindrops was studied by Philipp Lenard in 1898. He found that small raindrops (less than about 2 mm diameter) are approximately spherical. As they get larger (to about 5 mm diameter) they become more dough nut-shaped. Beyond about 5 mm they become unstable and fragment. On average, raindrops are 1 to 2 mm in diameter. The biggest raindrops on Earth were recorded over Brazil and the Marshall Islands in 2004  some of them were as large as 10 mm. The large size is explained by condensation on large smoke particles or by collisions between drops in small regions with particularly high content of liquid water.

Raindrops impact at their terminal velocity, which is greater for larger drops. At sea level and without wind, 0.5 mm drizzle impacts at about 2 m/s, while large 5 mm drops impact at around 9 m/s. The sound of raindrops hitting water is caused by bubbles of air oscillating underwater. See droplet’s sound

Generally, rain has a pH slightly under 6. This is because atmospheric carbon dioxide dissolves in the droplet to form minute quantities of carbonic acid, which then partially dissociates, lowering the pH. In some desert areas, airborne dust contains enough calcium carbonate to counter the natural acidity of precipitation, and rainfall can be neutral or even alkaline. Rain below pH 5.6 is considered acid rain.

Precipitation, especially rain, has a dramatic effect on agriculture. All plants need at least some water to survive, therefore rain (being the most effective means of watering) is important to agriculture. While a regular rain pattern is usually vital to healthy plants, too much or too little rainfall can be harmful, even devastating to crops. Drought can kill crops in massive numbers, while overly wet weather can cause disease and harmful fungus. Plants need varying amounts of rainfall to survive. For example, cacti need small amounts of water while tropical plants may need up to hundreds of inches of rain to survive.

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